Willemite mineralization was discovered in 1966 in the North Flinders Ranges of South Australia, in the course of a stream sediment sampling programme. Further work outlined a total of nine separate willemite occurrences in the Copley/Beltana area, and ten small deposits in the Toondana area south of Parachilna._x000D_
Mineable reserves of 1 000 000 tonnes grading 36.8% zinc were outlined in three deposits in the Copley/Beltana area and campaign mining of the Main Orebody commenced early in 1974. The main group of deposits all occurred within red, dolomitized Cambrian Ajax Limestone, and most are associated with significant thrust faulting. The area of the Main Orebody group of deposits has been intensely fractured, and the surrounding dolomites are often brecciated and contain up to 5% zinc. Lead and arsenic mineralization are minor components of the main group of deposits. Masses of Middle Proterozoic Willouran Formation crop out adjacent to or close to most of the deposits in the Copley/Beltana area. The Willouran is frequently highly sheared, brecciated, and often contains large inclusions of younger formations. It is believed that most of the Willouran outcrops represent piercement structures.