The Dittmer process for the debismuthising of lead by electrolysis beneath molten caustic soda has been scaled up to 100 kg lots for batchwise operation and to 20 kg per hour for a continuous flow of lead. Bismuth was decreas- ed from 0.03 to less than 0.005 wt. per cent for an electricity consumption of 220 kWh per ton of lead. Lower bismuth levels may be readily achieved if required.