X-ray fluorescence spectrometry is used videly for routine quality control of the mining, )lending and agglomeration of iron ores. Most )f the procedures used, cannot tolerate significant changes in matrix composition or be Lpplied to a wide range of elements. Accord- ngly, a graphite briquette technique which is Lpplicable to some fifty elements in widely Tarying iron ore matrices is described. The ignificant advantages are suitability of the ame preparation for both optical emission and -ray spectrometry, a complete elemental overage for the range 5bcg/g to 100%, and the recision and accuracy of the methods are om.parable with the standard chemical.methods hich have been superseded in the authors' boratories. The proposed methods become ore attractive and economical as more prehensive information is sought.