The start up operations of Western Mining Corporation's Kalgoorlie nickel smelter encountered troubles due to the high magnesia content of the concentrates. The flash smelter slags, with higher than normal magnesia content, had a much higher melting point than the normal low-magnesia, predominantly fayalite slags usually produced in nickel smelting. Investigations were made of the structures, melting points and viscosities of the Kalgoorlie smelter slags, as produced, and with additions of silica or lime.