A viable flow sheet of the sorption-flotation technology for gold recovery from low-grade ores and concentrates using powdered activated carbon modified by organic compounds as the sorbent-bearer has been developed. The powdered activated carbon, with high kinetic ability and sufficient specific area, was selected as the all-purpose gold cyanide complex-bearing sorbent which is active during flotation. To improve carbon adsorption capacity and to provide the required floatability its porous structure was filled with a quaternary ammonium compound which can extract gold cyanide complexes and render additional flotation properties to the carbon.
To optimise the process and to simplify the layout, adsorption and flotation processes were carried out simultaneously in a mechanical flotation cell.
The proposed technology was used for extended and pilot-plant tests of sorption-flotation gold recovery from 0.6 g/t Au final tailings and 2.0 g/t Au gravity tailings. The extended tests were carried out on Taseevskaya (Chita Region) flotation tailings, whereas pilot-plant tests were conducted on Kommunarovskaya (Krasnoyarsk Region) gravity tailings passing to cyanidation, followed by processing with filtration technology. Additional gold recovery from Taseevskaya final flotation tailings was 50.8 per cent. Gold recovery from Kommunarovskaya final gravity tailings was 92.5 per cent. Compared to the complete sludge process conventionally used at the plant, gold recovery was increased by 7.5 per cent due to lower gold losses in the liquid phase and conversion of the refractory non-cyanided metal into a carbon concentrate.
This paper presents the experimental results of gold adsorption onto powdered activated carbon modified with quaternary ammonium compounds (sorbent-bearer) as well as sorbent-bearer flotation with various collectors from cyanide solutions and pulps.