Improving liquid blending operations in production plants is of paramount importance in many industries like mining, oils, petrochemicals and food. For accurate blending of different types of process streams, like homogeneous, heterogeneous, cold or hot streams, it is essential that the composition can be accurately monitored in real time. Advances in energy dispersive X-ray fluorescence (EDXRF) technology offers the possibility to apply XRF for online elemental analysis. In this paper we discuss an online EDXRF analyser for accurate blending control in many industries.EDXRF has the advantage that multiple elements can be measured simultaneously over a wide concentration range of wt per cent down to a few mg/kg, for elements between sodium (Na) and americium (Am) in the periodic table. To reach the desired accuracy and precision in an online XRF analyser, it is important to bring a representative and homogeneous sample of the process flow into the optical path of the analyser. The combination of a laminar flow cell design and advanced EDXRF technology leads to low detection limits and high performance. The obtained precision and accuracy allows for much tighter process control. In this paper we present two examples of industrial applications.CITATION:Zoontjes, M G C, van der Maten, T, Kempenaers, L and Knig, U, 2017. Online X-ray fluorescence spectrometer for accurate monitoring and improving blending sharpness in liquid production processes, in Proceedings Eighth World Conference on Sampling and Blending , pp 235-238 (The Australasian Institute of Mining and Metallurgy: Melbourne).