A stibnite concentrate from Golden Spec (WA) was subjected to a series of tests involving high pressure cyanidation and pressure oxidation followed by conventional cyanidation. The concentrate, whose gold content was 18.1 g/t, yielded only eight per cent of the gold when leached directly by a standard 24-hour cyanidation test. The recovery was increased to only 15 per cent when pressure cyanided under the following conditions: ambient temperature, 2000 kPa oxygen pressure, two hour retention time and 30 per cent w/w solids pulp density. This poor response to pressure cyanidation emphasised the refractoriness of the material. Evidence of the fine distribution of the gold through the concentrate, from measurements of the particle sizing distribution and the gold analyses of the individual fractions, also suggested that this concentrate was highly refractory. Pressure oxidation of the concentrate at elevated temperatures followed by cyanidation yielded recoveries as high as 94 per cent. However a preoxidation treatment under the following conditions was necessary: 230C, 2000 kPa oxygen pressure for a period of four hours.