This paper explores options worthy of consideration in the management of S02 produced from the gold roasting operations at Kalgoorlie. Some of the options have relevance to other sources of SO2 in the region, eminating from nickel smelting operations. The paper considers the following options: 1. Capture of SO2 within the roaster where sulphur-containing reaction products are mixed with the calcine. 2. Processes in which the sulphur-containing products are bled separately from the stack for further treatment or for dumping as a waste. These include: Seawater-based scrubbing of SO2; Sulphuric acid manufacture as a feedstock for fertiliser production or for leaching of bauxite; its use as Caro's acid: and the production of value-added sulphur-containing reagents eg liquid S02 and sulphonic acid.