The process uses sodium hydroxide and sodium nitrate reagents as in conventional Harris refining plants, selectively removing the arsenic to the caustic phase at an operating temperature of 420-450C. A novel feature of the process concept is continuous treatment of loaded caustic slag for recovery of arsenic as a sandy crystal product suitable for further processing to arsenic trioxide. A large pilot plant was constructed and operated over a period of 3 years to develop materials handling techniques and equipment components and to prove the concept. Stable operations were achieved at equivalent capacities of 200 tonne/yr arsenic removal. The process is being considered in plans for expansion of bullion softening capacity at Port Pirie.