In the present work, the process of dephosphorisation of stainless steel was developed in laboratory scale by adopting a high frequence induction furnace, using BaCO3 base flux. By using BaCO3 - CaO - BaC12 - Fe2O3 Flux of about 110 g/Kg-metal, 30 per cent dephosphorisation degree was obtained a stainless steel containing 18,8 per cent Cr and carbon between 0,08 and 2,0 per cent. In addition, a dessulfurisation degree of 89 per cent was achieved too.