The kinetics of desorption of nitrogen from molten iron were investigated using the electromagnetic levitation technique. The respective influences of gas flow rate and surface active element (S) were examined. A second order behaviour with respect to the nitrogen concentration in the melt prevailed at all experimental conditions. Sulphur had a marked inhibiting effect on the desorption rate. The experimental results on the rates of nitrogen desorption have been interpreted with the aid of a reaction mechanism consisting of a sequence of elementary steps.