Cementation has been widely used in several hydrometallurgical processes for recovering gold and silver from process liquors. The process is electrochemical in nature, in which gold and silver are precipitated from the solution using less noble metals such as zinc, iron and copper. This paper summarises the current practice of gold cementation from cyanide liquors using zinc powder. Various developmental studies on the cementation of gold and silver from various systems (chloride and bromide) are also reported.