The mining residues at the abandoned copper mine site Pea de Hierro, located at the headwaters of the Rio Tinto, contribute substantially to the pollution of the river with high loads of Fe, As, Pb, Zn and Cu. The pH of the outflow ranges from 0.5 to 2.4 in the dry and wet season, respectively._x000D_
One heap composed of alternating layers, which were deposited parallel to the slope, was investigated in detail. Unsorted blocky to fine materials including gossan material, pyritic volcanics, ashes from pyrite combustion and slate were observed here. The top of the heap has a gentle slope and a hill contouring channel-rip morphology. The initially rugged surface was smoothed by heavy rainfalls filling up the pores of the blocky material with fines. These fines are capable of storing the water for a prolonged time, providing an extended reaction time close to surface in a dry climate at extremely low pH conditions (one to four). All minerals, pyrite, mica, barite and even quartz (probably due to F released from dissolved mica) have been digested and silica gel precipitates have formed a stable and quasi impermeable 100 m layer with very low porosity (<5 area per cent, estimated using scanning electron microscopy (sem) imaging). the silica layer itself is covered by fe-oxy-hydroxide (ie feooh) coating (10 m) and seals a 1 - 5 mm thick stable hardpan. this hardpan covers the channels and part of the rips almost entirely, guiding the rainwater subhorizontally towards slopes and sinkholes. by geoelectrical measurements, a 3d-resistivity model of the internal structures and the bedrock relief underlying the heap was generated. internal structures relate to lithological changes in a number of layers. zones of low resistivity may be attributed to washed-in fines within the mega pore system, whilst zones of high resistivity close to the surface probably reflect the advanced stage of drying beneath aging hardpans. the water movement at the surface was investigated by an artificial precipitation experiment with monitoring of the subsequent changes in resistivities.>