The Kalahari Manganese Deposit in South Africa accounts for 80 per cent of the world's land-based mineable Mn reserves. Although the ores are primarily mined for export, South Africa is the world's third largest producer of ferromanganese and ferrosilicomanganese alloy, both of which are derived from the smelting of these ores. Mineralogical analysis has traditionally been forsaken for bulk chemical assaying in quality control of smelter feeds, principally because quantitative data could not be easily produced. Yet, mineralogy plays a vital role in determining smelting behaviour, which in turn has economic implications when aspects such as energy and reductant consumption are considered._x000D_
Smelting is an endothermic process, and the amount of energy input required is dependent on the minerals present in the ore, as well as their relative proportions. Further, knowing the bulk Mn oxidation state in the ores allows for calculation of the amount of oxygen that must be driven off to produce alloy, and hence the amount of reductant required. Additionally, certain minerals can be correlated with potentially deleterious elements, so that ore mineralogy can indicate penalty element distribution._x000D_
Mineral abundance analysis was conducted on ores from the Kalahari Manganese Deposit using quantitative X-ray powder diffraction. Rietveld refinement using a fundamental parameters approach was applied to micronised ore samples. The mineral percentages obtained were validated using mineral chemical data together with bulk major element data derived from ICP-OES. Bulk oxidation state partitioning was then carried out knowing the Mn valence in the minerals. The results show potential for implementation of the proposed method on a smelting plant, where ore blending could be then implemented to achieve consistent feed compositions to smelters. Selective mining could also be undertaken to obtain desirable ore compositions for domestic or international markets.