Although most N.S.W. coal mines contain large amounts of combustible materials such as coal and timber, the introduction of mechanisation has extended the range of combustible materials now found underground. The role of combustible material in a fire is not clearly understood and as a result the assessment of these materials for flammability by small and large scale tests is doubtful. Extensive research has been carried out on the toxic and irritating gases evolved during the combustion of plastics. However, most autopsies report death due to carbon monoxide inhalation because the combined toxicity of smoke and fire gases is unknown.