In a coal mine there are many substances capable of ignition under certain circumstances, which can be placed in the following groups: ordinary combustible solids, dusts, liquids and vapours, gases, metals and plastics. There are many factors influencing ignition, including temperature, minimum ignition energy, particle size, explosion pressure level, rate of pressure rise, specific energy content and also explosive limit. Not all are applicable in every case. Frictional ignition of methane is an accident statistic of increasing concern and is considered in some detail. Practical measures that can be taken to reduce the incidence of frictional ignitions are considered, and also possible ways of ignition suppression.