The main techniques for removing phosphorus as an impurity element in iron ores are physical separation (eg magnetic separation, flotation) and chemical separation (acid leaching, alkaline leaching and bioleaching) processes. When phosphorus occurs in iron ores as phosphate minerals (eg apatite), physical separation techniques are available to remove the gangue minerals from iron ores. On the other hand, chemical separation techniques are suitable for reducing phosphorus levels when phosphorus is associated with iron oxides and hydroxide minerals (eg hematite and goethite) in iron ores. In this study, the dephosphorisation behaviour of high‐phosphorus iron ore was investigated using a combined alkaline roasting and water washing route. Roasting experiments were conducted in a laboratory electric muffle furnace using various concentrations of sodium hydroxide (0–50 g/kg-ore) at different temperatures (100–800°C), varying prolonged roasting times (0–2 h), and different particle size fractions (-45 – -250 μm) of iron ore. Subsequent water washing experiments were employed at various pulp densities (30–1000 g/L) and different times (30 s – 60 min) at ambient temperature. Hematite and goethite were the main minerals in the high-phosphorus iron ore identified using X-ray diffraction (XRD) analysis. The iron ore assaying 63.40 mass % Fe (total), 0.240 mass % P, 4.53 mass % SiO2, and 4.87 mass % Al2O3 were determined using X-ray fluorescence (XRF) analysis. The results showed that the dephosphorisation rate of the iron ore was reached 40 per cent under roasting with 50 g/kg-ore NaOH at 300°C for 2 hours followed by water washing for 30 s with a pulp density of 300 g/L, reducing phosphorus level from 0.240 mass % to 0.142 mass %. At the same time, the iron grade was reduced from 63.4 per cent to 59.5 per cent, caused by an iron loss. Results suggest that the phase transformation of goethite induces the dephosphorisation of high-phosphorus iron ore under alkaline roasting conditions