The value of Raman spectroscopy to undertake mineral and chemical characterisation of iron ores was assessed by applying the technique to representative samples of banded iron-formations (BIF) and a BIF-derived, martite-goethite ore. The common iron oxides haematite, magnetite and goethite as well as gangue minerals such as quartz and carbonates all show distinct Raman spectra that enables these phases to be easily detected and mapped in situ for either samples prepared as polished blocks or unprepared material._x000D_
Raman spectroscopy also offers the potential of in situ chemical characterisation. Shifts in the excitation bands of carbonate detected in BIF were related to the Mg content of Fe-carbonate and confirmed the first world-wide occurrence of a high Mg-bearing siderite (pistomesite) in BIF.The discriminatory power of Raman spectroscopy coupled with the potential of the technique to offer large-scale (volumetric) characterisation of iron ore will be of great value not only to the existing BID and CID ore types, but also to the newly emerging magnetite iron deposits (MID).