Asian steel mills are demanding iron ore with specific chemical, mineralogical, metallurgical and environmental properties to warrant that the ore is of the greatest quality. As a result, a toolkit of analytical techniques becomes important. Hyperspectral analyses of iron ore cores and chips using a HyLogging system are now routinely undertaken by BHP Billiton Iron Ore in Western Australia for banded iron formation-hosted iron ores and channel iron deposits to better characterise their iron ores. Objective information can now be expanded by adding new sensors. The current HyLogging system provides point analysis reflectance spectra and a red-green-blue high-resolution image, while recent developments, such as hyperspectral imaging using the Corescan system, now provide full spectral image and surface topography. The addition of Raman spectroscopy provides the ability to detect and quantify quartz and magnetite (or maghemite) and cross validate hyperspectral information on hematite and goethite and aluminium substitution in the iron oxides. Micro-X-ray fluorescence mapping also adds chemical information appropriate for cross validation with the aforementioned methods. This paper demonstrates the value of combining these techniques for an optimum characterisation of iron ore.CITATION:Ramanaidou, E R and Wells, M A, 2015. A new toolkit for iron ore characterisation, in Proceedings Iron Ore 2015, pp 587-590 (The Australasian Institute of Mining and Metallurgy: Melbourne).