X-ray fluorescence (XRF) is a widely accepted technique for the elemental analysis of iron ores and their concentrates. Wavelength-dispersive, or WDXRF, and energy-dispersive, or EDXRF, spectrometers offer distinct advantages for particular applications, elements and concentration ranges and are, therefore, more complimentary than people might realise. A key example is the ability of EDXRF to identify, and often quantify, unexpected elements in production samples that would typically be missed by routine WDXRF. In this paper we discuss recent technological advances in XRF and present a novel application example that demonstrates the additional technical and practical benefits of using both EDXRF and WDXRF to characterise iron ores and concentrates.CITATION:Tsouris, C, Komelkov, A and Rayner, M, 2015. A novel approach to the characterisation of iron ores and concentrates using recent advancements in wavelength- and energy-dispersive x-ray fluorescence spectrometers, in Proceedings Iron Ore 2015, pp 591-594 (The Australasian Institute of Mining and Metallurgy: Melbourne).