The light microscopic study of the physical structures of coal and associated mineral matter is an important technique in providing information on the characterisitics and possible behaviour of coals in industrial processes. However the ultrafine nature of coal and mineral particles together with the limits of resolution of the light microscope restrict such studies. Scanning electron microscopy (SEM)with its better resolution and higher magnifications is the means by which further information on coal properties can be obtained. An associated energy dispersive X-ray specrometry (EDS) method allows non-destructive in-situ chemical analyses to be carried out at the same time.