The carbothermic chlorination of titaniferous materials such as rutile, synthetic rutile (SR), upgraded slag and ilmenite in a fluidised bed is an established commercial process. In this work, ilmenite sourced from the Murray Basin area of South Eastern Australia was chlorinated and an assessment of the chlorination characteristics of the ilmenite, in terms of pre-treatment, type of reductant and reaction time was made. Selective chlorination of Murray Basin ilmenite to remove Fe and Mn was achieved in this work. A synthetic rutile sample containing around 93 per cent TiO2, one per cent Fe2O3 and 0.5 per cent MgO was produced at a chlorination temperature of 1000C with around 25 per cent loss of Ti as TiCl4. Raising the reductant to ilmenite ratio in the chlorination reactions increased the amount of Ti chlorinated. However, complete chlorination of Murray Basin ilmenite to produce FeCl3 and TiCl4, was not achieved under the conditions used in this work. Pre-oxidation of Murray Basin ilmenite before chlorination had little affect on its reactivity, compared with as received' ilmenite. In contrast weathered West Coast ilmenite chlorinated appreciably better than West Coast primary ilmenite, in terms of bed residues remaining and amounts of elements removed. The presence of large amounts of Mg and chrome spinel grains in the Murray Basin ilmenite used in this study are likely to make it difficult to chlorinate directly in a commercial chlorinator. However, this is not to say these ilmenites will be unsuitable for chlorination applications. Further work is needed in the separation of Mg and chrome spinel grains from Murray Basin ilmenites and the products resulting from these tests could then be assessed in terms of chlorination performance, so that further processing options can be explored.