Three transient phenomena have been observed and experienced in the operation of large solvent extraction mixer-settlers. These relate to the ability of the settler to discharge streams with low entrainments arising from different phase separation problems'. The operation of large-scale laboratory and commercial solvent extraction settlers has been shown by a number of workers to be a dynamic process, especially at the feed end. Circulating flow patterns are common in all three organic, aqueous and emulsion phases. The circulating patterns in deep dispersion bands in long settlers are believed to form roll fronts that can travel down the settler length within the bounds of the dispersion band. Various physical models are proposed to illustrate the formation and movement of roll fronts within the dispersion band. Another transient phenomenon has been observed in commercial settlers operating without any dispersion band. Entrainment of the continuous phase in the advancing dispersed phase is at high and erratic levels. This supports the conventional separation model, which recommends the presence of a significant depth of dispersion band to filter' the secondary haze from the bulk separated phases. The third transient is the position and shape of the dispersion band within the settler. Large commercial settlers have been shown to exhibit high variability in both these aspects of the dispersion band. The elimination of all three transient phenomena in commercial settlers has been shown to be effective with an in-settler media of coarse size and moderate specific surface area. The effect of the media is two-fold: it dissipates both the circulating flows and the forward velocity of any roll fronts, and creates a stable deep dispersion band at the feed end that serves to trap secondary haze from the primary coalescence process. It is effective in treating both types of transients involving non-existent or excessive dispersion band depths. The media serves to enhance coalescence by providing a static surface of intermediate surface tension on which droplets can collapse. The random nature of the media also provides multiple stream splitting and re-combination, that presents further drop to drop and drop to media impingement, which in turn promotes coalescence.