Conference Proceedings
Non-ferrous Smelting Symposium: 100 Years of Smelting and Refining Operations in Port Pirie, SA September 1989
Conference Proceedings
Non-ferrous Smelting Symposium: 100 Years of Smelting and Refining Operations in Port Pirie, SA September 1989
The Effect of Process Variables on Electrowinningt Cadmium and Silver
The electrolytic recovery of metals from solution requires an understanding of the characteristics of the particular system employed, and the current efficiency and morphology of the deposit are influenced by such factors as cell design, metal ion and supporting ion concentration, acid concentration, temperature, impurity levels and cell design. The electrolytic deposition of both cadmium and silver present individual difficulties, and special cell designs are used for each of these metals. It was found that cadmium deposition was plate-like at lower cadmium concentrations, and at higher current densities. The presence of zinc in the electrolyte promoted nodular growth._x000D_
Current efficiency remained high even at 50C in contrast to published information. Silver deposition morphology was relatively unaffected by changes in silver concentration, pH and current density. Current efficiency was reduced as temperature was increased.
Current efficiency remained high even at 50C in contrast to published information. Silver deposition morphology was relatively unaffected by changes in silver concentration, pH and current density. Current efficiency was reduced as temperature was increased.
Contributor(s):
R Dunn, K Watson, D M Pollard
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- Published: 1989
- PDF Size: 1.01 Mb.
- Unique ID: P198906034