This paper considers two particular empi- rical models for the processes of the generati- on of hydrochemical zoning and epithermal near- surface mineralization of mercury-antimony-arse- nic formation in the discharge area of the Uzon Caldera ore generating hydrothermal system in Kamchatka. Vertical and horizontal hydrochemical zo- ning is caused by mixture of infiltration waters of the surface formation with fluid of chloride- sodium composition which are supplied up the-zo- ne of deep fault. Ore formation is caused by simultaneous existence of two geochemical barriers, namely oxidizing and reductive. The first barrier is determined by the-level of ground waters. The second one forms under the clay-opal screen un- der the influence of two factors, namely the inflow of deep reduction sulphur compounds (which are transported together with arsenic, antimony and mercury) and the generation of hyd- rogen sulphide as a result of sulphur- and sul- phate reduction. X-ray-amorphous phase of orpi- ment composition and realgar phase are formed, respectively, on the oxidizing and reductive Barriers.