The two major massive sulphide deposits in the Silurian rocks of southern NSW, Captains Flat and Woodlawn, differ from classical Kuroko deposits in several ways, e.g. they lie on the flanks of felsic volcanic piles in volcano-sedimentary marine sequences, are relatively thin and large compared to individual Kuroko deposits, show prominent banding in lead-zinc ore, and contain arsenopyrite. Qualified stuctural and stratigraphic correlations of the various fault-bounded remnant Silurian sequences that host these deposits provide the basis for a new interpretation of the regional geological setting that also differs from that of the Kuroko deposits (Ohmoto, Tanimura, Date, Takahashi, 1983), and sheds further light on the distribution of volcanogenic massive sulphide deposits in the Silurian rocks of NSW.