The combustion characteristics of Australian coals which contain high inertinite have been studied in a laboratory drop tube furnace and a Thermogravimetric Analyser. The pyrolysis chars and combustion residues were microscopically characterised using a modified coal petrography technique. Results indicated that the overall burnout of inertinite-rich Australian coals under pulverised fuel combustion conditions could be generally within a range of 97 - 99 per cent burnout. The studies showed that poor coal burnout cannot be generally related to high inertinite content in the Australian coals. The extent of coal burnout varies from coal to coal and vitrinite as well as inertinite may contribute to the unbumt chars in combustion residues. Combustion conditions had greater influence over char formation and coal burnout than the coal properties. However, under similar pf combustion conditions, coal rank and coal maceral composition had a strong influence over the coal combustion behaviours and final coal burnout. Simple correlations using coal properties may be used but with caution to determine coal volatile release and burnout at high temperature and rapid heating conditions.