During the next five years Denmark will implement a significant reduction in the national CO2 emissions to fulfil the Kyoto Protocol. The energy sector is central for achieving this goal and extensive use of renewable energy is the most important single factor contributing to reduce emissions of greenhouse gases. Denmark's renewable energy sources comprise wind energy and biomass. Wood chips and straw are the dominant type of biomass in Denmark. More than 500 000 tons of wood chips are used annually, currently with rapidly growth prospects. This contribution focuses on sampling of wood chips.