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Conference Proceedings

Smelting and Refining Operators' Symposium, North Queensland

Conference Proceedings

Smelting and Refining Operators' Symposium, North Queensland

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Arsenic Removal from Copper Electrolytes by Solvent Extraction

The development, design, construction and operation of the new Solvent Extraction/BCA process plant at Copper Refineries Pty. Ltd., Townsville is described._x000D_
The process offers substantial savings in electrical power costs, improvements in plant hygiene, and a lowering of materials handling costs compared with conventional electrowinning technology._x000D_
The solvent extraction process extracts arsenic from copper Tank House electrolyte using a tributyl phosphate (TBP) - kerosene solvent. The plant incorporates four extraction stages, two scrub stages, and three stripping stages to produce an arsenic-bearing low-acid strip liquor. This strip liquor is mixed with copper sulphate, and neutralized with ammonia to form a copper (II) arsenic (V) crystalline product, bicupric arsenate (BCA). This product is then used in the manufacture of chromated copper arsenate timber preservatives (Royston 1982).
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  • Published: 1985
  • PDF Size: 0.372 Mb.
  • Unique ID: P198501002

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