The monosaccharides glucose, galactose and arabinose, and the polyols glycerol and mannitol (0.1 Ufo WIV) supported pure and mixed culture heterotrophic bacterial manganese leaching of solid pyrolusite (MnO2, 2% W/V) to yield 14-38 mg/litre manganous ion in 3 days from a simple mineral salts media at 30C. Supplementation of pure bacterial isolates growing on glucose with soluble intracellular photosynthate from freshwater algae (0.07 g/l carbohydrate) and marine algae (0.11 g/l) led to an improvement in Mn++ yields of 24 and 100 per cent respectively. Extracellular products of the freshwater algae (0.3 g/l carbohydrate) boosted recoveries by 57 per cent.