Rajasthan of western India blessed with rich base metal and phosphorite deposits. The biogeochemical and geobotanical methods of mineral exploration are greatly used in parts of Rajasthan Zawar, Khetri and Ambaj multi-metal project Gujarat and Jhamarkotra phosphorite deposit. These principles are exclusively based on certain assumptions about the anomalous chemical composition in plants and distribution and migration of indicator elements. Biogeochemical studies for lead zinc deposit of Zawar group of mines were carried out to locate the probable accumulators which could help in prospecting for these metals. The important roots of Impatiens balsamia plants contain 735 mg. of cadmium and crotolaria linifolia 603 mg., melhania futteyporensis 626 mg. lindenbergia muraria 443, celosiu argentia 360 mg. In the Khetri copper belt the vegetation is scanty and the species includes Acacia arabica, zyzypus jujuba and cactus euphorbia.