This paper describes a case history of using an integrated geochemical and hydrogeological approach to predicting solute transport from gold mine tailings in highly fractured volcanic terrain. Two modes of transport are identified, namely discrete fissure flow and diffuse seepage through the intervening weathered rock. A simple mass balance approach is used to predict concentrations at points of emergence because most of the seepage migration will be by way of the discrete fissures where advective transport will predominate. The mass balance method has been modified to allow for natural degradation of weak acid dissociable cyanide. The long term effects of diffuse seepage are also examined.