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Conference Proceedings

World Zinc '93

Conference Proceedings

World Zinc '93

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Recovery of Metallic Zinc from Bath-Smelting Gases - Thermodynamic Considerations

Lead blast furnace slags contain typically 10 - 20 mass per cent Zn. The zinc can be recovered by slag fuming, in which a powdered coal/air mixture is injected into a molten slag bath. Volatilised zinc is recovered as zinc oxide from the gas and processed hydrometallurgically to produce zinc metal. The ISASMELT continuous lead smelting process in operation at Mt Isa produces a slag containing about 12 per cent Zn which is currently granulated and stockpiled. This slag could flow to a further bath-smelting reactor for continuous zinc fuming. Rather than collecting the zinc as fume from such a process, one option would be to recover it using a lead splash condenser. The success of this operation would depend on the composition of the gas produced, in particular the concentrations of gases capable of reoxidising zinc vapour, viz, carbon dioxide and water vapour. The aim of this investigation was to determine the smelting conditions for a bath-smelting process such as ISASMELT or SIROSMELT which would produce a gas similar in composition to that from an Imperial Smelting Furnace by thermodynamic modelling of the process using the CSIRO Thermochemistry System. It was found that such a gas could be produced if coal injection and oxygen enrichment of the combustion air to at least 40 per cent 02 were used. However, the off-take gases must be conditioned by addition of methane to reduce the water vapour content to acceptable levels. An addition rate of ten per cent of the off-gas flowrate was found to be adequate. Addition of methane to the off-gas had the added advantage of cooling the gas from the bath temperature to a temperature suitable for normal lead splash condenser operation.
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  • Published: 1993
  • PDF Size: 0.592 Mb.
  • Unique ID: P199307049

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