The behaviour and deportment of indium during the precipitation of sodium jarosite from Fe2(S04)3 - Na2SO4 solutions were investigated. Indium is readily precipitated with sodium jarosite, and the extent of In precipitation increases as the In concentration of the solution increases. It was shown that In 3+ substitutes for Fe 3+ in the jarosite structure to form a nearly ideal solid solution series. On a molar basis, the precipitation of Fe is slightly favoured over that of In, and the difference is reduced as the pH increases. Sodium jarosite precipitation becomes kinetically rapid at temperatures >70C, but increasing temperatures in the range 70 to 150C affect neither the relative precipitation of In and Fe nor the composition of the jarosite product. Low Na2SO4 concentrations result in reduced product yields and jarosite precipitates in which H3O' > Na+. The hydronium-rich precipitates have reduced In contents. Increasing the ZnSO4 concentration of the solution slightly increases the quantity of jarosite formed and results in the incorporation of -0.3 per cent Zn in the jarosite structure. Otherwise, the presence of ZnSO4 has no significant effect on the composition of the jarosite. Seeding accelerates the rate of jarosite precipitation but has a negligible influence on the deportment of In. The jarosite precipitation reaction at 98C is relatively rapid and near-steady state conditions are achieved in - 6 h even in the absence of seed. The initially precipitated jarosite is slightly enriched in In with respect to Fe. The ferric ion concentration of the solution has a significant influence on both the amount of jarosite formed and its composition. In particular, the jarosites precipitated from dilute Fe3+ media have significantly enhanced In contents. Hence, it may be possible to recover - 25 per cent of the dissolved In, at the 1000 mg/L level, in a jarosite precipitate assaying - ten per cent In by the controlled oxidation-precipitation of sodium jarosite from a ferrous sulphate processing solution.