A major advantage of the Sherritt Zinc Pressure Leach Process is the conversion of sulphide sulphur in zinc concentrate to elemental sulphur during pressure leaching. Elemental sulphur can be recovered as a marketable byproduct by flotation of the leach residue, and melting and filtration of the sulphur flotation concentrate. The behaviour and deportment of sulphur during pressure leaching, flotation, and melting and filtration are discussed in this paper using data obtained from the treatment of a wide variety of zinc concentrates in the laboratory miniplant at the Sherritt Research Centre. The quality of the elemental sulphur byproduct and a process for purifying the sulphur are also Presented.