Kaolin used as an industrial mineral, especially that in the paper-manufacturing industry, must be of fine size, with high brightness, a low impurity content, and good crystal shape. However, in most kaolin deposits there are various impurities which have a very bad effect on the quality of the kaolin. Therefore, it is necessary to remove these impurities from kaolin ore. Owing to their similar surface properties, the separation of kaolin and iron oxide minerals, especially microkaolin and iron oxide minerals, has been regarded as difficult. The iron oxide minerals often intergrow with kaolin in fine and complicated forms, such as thin films, which make separation difficult. In order to overcome this difficulty, many workers have suggested various treatment methods and obtained great success. Based on research work by Fuerstenau (1980), Huang, Li and Hu (1984), Hui and Wei (1991), Shergold (1978), and Zambrana et al (1974), we have investigated a two-liquid flotation technique for iron removal from kaolin and obtained some success.