The flotation properties of acetic acids modified by xanthic and dithiocarbamic fragment in regards to copper and ferrous minerals and their noble metal containing ores have been investigated. The effectiveness of the co-using of these reagents with xanthates and dithiocarbamates has been shown, ie using of proposed reagent regimes for the flotation of Au-containing ores increases gold recovery by 4.2 - 4.7 per cent, and in the case of flotation of copper Re-containing ores copper recovery increases by 3.3 per cent, rhenium recovery - by 15.5 per cent. The mechanism of the action of these reagents has been explained by the data of UV and ESR-investigations of their sorption on mineral surface. The information on structure and properties of co-ordination compounds of some metals with (Diethyldithiocarbamato) acetic acid were used also for the explanation of flotation mechanism.