An extensive laboratory campaign was conducted to find a suitable water soluble collector to replace diphenylguanidine (DPG) in the matte separation process. The examination of the collectors was done by measuring the rate of flotation and the best candidate collectors were selected on the basis of the rate parameters. As a result of this search mercaptobenzothiazole (MBT) was selected for a plant trial. A plant trial of two weeks duration confirmed that MBT will produce separations at least as good as those obtained with DPG.