The disposal of residues from coal preparation and processing will to an increasing extent require investigation and consideration of the environmental problems resulting as a consequence of this. Different authors (Diingelhoff and Plankert, 1983; Hasenpatt, 1985; Szczepanska and Twardowska, 1987) have concentrated primarily on the content and the mobilisation of inorganic contaminants such as chlorides, metals and heavy metals from spoil tips, while no publications have yet been found on the question of a possible emission of organic contaminants (PCB, PAH, HC HC) from processing residues. Here the flotation residues in particular are able to bind larger quantities of organic contaminants by physi-sorptive means because of their large specific surface and, after disposal, to be re-emitt than into the environment. The flotation agents used in coal flotation are mixtures of technical distillation products with a correspondingly fluctuating composition. As Hey, 1986 showed, they may contain, in addition to the main components (n-alkanes, alcohols, surfactants), over 50 individual trace substances. In conjunction with the structural-chemical similarity of the individual components, this complicates the quantitative analysis of individual components considerably. For the analysis of hydrocarbon content of flotation products by means of extraction with organic solvents in accordance with DIN 38408, H18, the difficulty arises, besides the insufficient sensitivity at low concentrations, that geogeonic hydrocarbons are extracted from the coal as. well and the analysis results are thus falsified. These problems were overcome by the application of the 14C radiotracer method where certain components of the flotation agents are marked with radioactive carbon (14C). By measurement of the radioactivity of solid and liquid samples, the concentration of the marked substance can be measured very sensitively and precisely, whereby the accumulative measurement of similar organic substances is ruled out. Thus the reaction path of certain substances in complex reagent mixtures such as flotation agents can be traced excellently and the conceivable environment burden resulting from flotation tailings disposal can be estimated. In this paper, the adsorption behaviour of typical components of coal flotation agents are investigated for different coals and types of gangue material, the reagent content of flotation concentrates and tailings, as well as the mobility of the reagents adsorbed onto solids. The knowledge of adsorption and desorption mechanisms of unpolar hydrocarbons emulsified in water to solids are also of particular interest for the understanding of processes of organic soil contamination and for the further development of washing processes for oil-contaminated soils.