The basic separation phenomena taking place in film concentration processes are studied through a kinetic-probabilistic approach. This approach is based on the fact that the particle velocity in the film separation phenomena is a random variable and may be defined by frequency distributions and probability laws. The approach requires: 1. development of probabilistic models for describing the behaviour of particles having different specific gravity and size along selected trajectories in the separating devices; 2. setting up an experimental procedure for determining the relevant frequency distribution curves at the exit of the separators for the particles mentioned above; 3. estimation of model parameters and model validation. In the paper, the model equations are given for the mass distribution of particles on the surface of separators, the mass distribution at the exits of shaking tables and the residence time distribution in channel type devices. The relation between residence time distribution and particle velocity distribution is derived. The test procedure has been defined and results are reported for the exit or residence time distribution in channels. A comparison between experimental and calculated frequency distributions is reported.