Among the problems of the flotation of sulphides by the thiol collectors is the dependence and varieties of the flotation starting with the time and oxygen contents in the slurry. For sulphides, the flotation stage follows after the electrocatalytic oxidation of the collector with oxygen on the surface of the conductor minerals. The necessity of the oxygen for sulphide flotation (Plaksin and Bessonov, 1957) is in accordance with a corrosion model of a collector surface sorption (Salamy and Nixon, 1954). As Golikov and Nagimyak (1961) showed, the sulphides possess catalytic activity which provides the autoxidation of the xanthates in the sluny to the dixanthogen. This stage can be rather protracted, which limits the speed of the total process. Disulphides constitute important collectors for the sulphide flotation and the optimal degree of the xanthate oxidation is about 20 per cent for different ores (Abramov, 1978) or, following Chanturiya and Nazarova (1977) the surface compositions for various sulphide ores are different and an optimal oxidation degree is variable from five to 25 per cent according to the ore nature. The optimisation of the surface composition is possible by application of the dixanthogens, or by a partial chemical, electrochemical, or catalytic oxidation of xanthates (Desains, 1847; Schall, 1896; Vigdergauz, 1989). According to Rand (1977) and Vigdergauz (1991) sulphides possess different catalytic activities for oxygen electroreduction. In neutral solutions, for example, the following decrease in the order: FeS2 (Fe,Ni)9S8 CuFeS2 FeS; Cu5FeS4 Cu2S; PbS (Vigdergauz, 1991). For the cases of low catalytic activities of the sulphides, the preflotation oxidation of xanthate could be useful to optimise the process kinetics.