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Conference Proceedings

XXV International Mineral Processing Congress (IMPC) 2010

Conference Proceedings

XXV International Mineral Processing Congress (IMPC) 2010

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Concentration of Igneous Phosphate Ores via Froth Flotation - Challenges and Developments

Igneous phosphate deposits located in tropical and subtropical regions of the world are characterised by low P2O5 grades, very diversified mineralogy and intensive lateral plus vertical variations in chemical composition, mineralogical assembly, rock texture, grain size, slimes content and morphology plus surface coating of apatite particles. Those variations characterise ore types with distinct behaviour in mineral processing plants. This work reviews the main challenges to concentrate those ores, addressing developed solutions. Apatite concentration requires long chain anionic collectors to conduct reverse flotation of barite (alkyl sulfate) before direct flotation of apatite (sarcosinate, sulfosuccinate and oleate) at basic medium. The long chain collectors decrease the surface tension of the flotation solution (gLV) and a particular value of 51 mN/m was found to promote the most selective separation between apatite/gangue at a particular plant. Effective control of the magnitude of gLV in industrial plants has not been realistic because there is a lack of reliable instruments to carry out in-situ measurements._x000D_
Regarding gangue depression by starch, a review is made on possible mechanisms that promote its remarkable ability to depress some minerals (Fe-oxides, ortho plus meta silicates and calcite) vis-a-vis others (quartz, apatite and layered silicates)._x000D_
Flotation recovery (R) of fine (2070 per cent) and inadequate hydrodynamic conditions within flotation cells are the main reasons for that behavior._x000D_
Once the best hydrodynamic conditions to float coarse particles are not the same to float the fine ones, flotation of coarse and fine particles is commonly conducted at separated circuits in industrial scale. Entrainment of very fine gangue particles is an important source of contamination of apatite concentrates, mainly when weathered ores are treated. In most cases, adjustments in flotation equipment (columns or mechanical cells) promote considerable improvement in the quality of final concentrates._x000D_
CITATION:Leal Filho, L, Martins, M and Horta, D, 2010._x000D_
Concentration of igneous phosphate ores via froth flotation - Challenges and developments, in Proceedings XXV International Mineral Processing Congress (IMPC) 2010, pp 63-76 (The Australasian Institute of Mining and Metallurgy: Melbourne).
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  • Published: 2009
  • PDF Size: 0.909 Mb.
  • Unique ID: P201007007

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