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Conference Proceedings

XXV International Mineral Processing Congress (IMPC) 2010

Conference Proceedings

XXV International Mineral Processing Congress (IMPC) 2010

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Stripping of Fe (III) from D2EHPA Using Different Reagents

The common way to extract Fe(III) from an organic solvent is by using concentrated acidic solutions. The stripping of Fe(III) from organic solvent Di-2-ethylhexyl phosphoric acid (D2EHPA) by hydrochloric acid (HCl) solutions has been found to increase with increasing the acid concentration._x000D_
However, the use of a concentrated acidic solution such as 6 M HCl can degrade the organic molecules. In this research, to increase the efficiency of Fe(III) stripping from D2EHPA, effect of some acids, salts and buffer solutions was studied. Influence of Tri-butyl phosphate (TBP) as modifier on the Fe(III) stripping operation was also investigated. According to the results, the best Fe stripping recovery was achieved in the presence of low acid concentration and the salts which was 72.4 per cent oxalic acid, 70 per cent ammonium oxalate and 75 per cent buffer of oxalic acid and ammonium oxalate. The results also showed a better recovery in the presence of the buffer rather than the salt. Finally, increasing the concentration of TBP, HCl and H2SO4 resulted in a higher stripping efficiency of Fe(III). However, in the presence of oxalic acid and its salts increasing the reagent concentration did not increase the stripping efficiency and at this condition, the recovery of iron remained constant._x000D_
CITATION:Akhlaghi, M, Rashchi, F and Vahidi, E, 2010. Stripping of Fe (III) from D2EHPA using different reagents, in Proceedings XXV International Mineral Processing Congress (IMPC) 2010, pp 255-262 (The Australasian Institute of Mining and Metallurgy: Melbourne).
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  • Published: 2009
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